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BORON DOPING AND POROSITY ENHANCE PHOTOCATALYTIC ACTIVITY OF GRAPHITIC CARBON NITRIDE FOR DICLOFENAC REMOVAL
Home Research Publications BORON DOPING AND POROSITY ENHANCE PHOTOCATALYTIC ACTIVITY OF GRAPHITIC CARBON NITRIDE FOR DICLOFENAC REMOVAL

BORON DOPING AND POROSITY ENHANCE PHOTOCATALYTIC ACTIVITY OF GRAPHITIC CARBON NITRIDE FOR DICLOFENAC REMOVAL

T G. N., T H. N., V H. H., M D. N., K V. N. T., H L. N. T., T L. L. T., T L. D., Dec-2024, In: TNU Journal of Science and Technology, 230, 06, p. 88-94

Overview

  • Giang N. T.
  • Hung N. T.
  • Hung H. V.
  • Dung N. M.
  • Van N. T. K.
  • Luong N. T. H.
  • Linh L. T. T.
  • Lan D. T.

Abstract:

Wastewater contains trace amounts of antibiotics and dye, which can harm

ecosystems and human health. This study presents a novel photocatalyst, borondoped

graphitic carbon nitride (B-g-C3N4), as a potential solution. Developed

through two steps using hydrothermal self-assembly and thermal polymerization,

B-g-C3N4 exhibits a distinctive tubular structure. The unique tubular structure

remarkably increases its surface area and optical absorption, effectively degrading

DCF under visible light. Compared to pure g-C3N4, the B-g-C3N4 material has a

slightly increased surface area (from 14.83 to 16.47 m2 g−1). Moreover, the

incorporation of boron into the g-C3N4 matrix narrows the energy band gap from

2.74 eV to 2.67 eV, allowing the B-g-C3N4 to absorb more effectively in the visible

light region. As a result, more electron-hole pairs are generated, effectively

initiating the photocatalytic degradation process. As a result, B-g-C3N4 exhibits

remarkable efficiency in degrading DCF, achieving nearly 99% elimination in 60

min under visible light illumination. The outcome emphasizes the potential of B-g-

C3N4 as a promising choice for environmental remediation applications.

Keyword(s): Supramolecular self-assembly Graphitic carbon nitride (g-C3N4) Diclofenac (DCF) Photocatalyst Visible light

Pages (from-to) 88-94
Journal TNU Journal of Science and Technology
Volume 230
Issue number 06
Publication status Published - Dec-2024
ISBN 1859-2171