BORON DOPING AND POROSITY ENHANCE PHOTOCATALYTIC ACTIVITY OF GRAPHITIC CARBON NITRIDE FOR DICLOFENAC REMOVAL
Overview
Abstract:
Wastewater contains trace amounts of antibiotics and dye, which can harm
ecosystems and human health. This study presents a novel photocatalyst, borondoped
graphitic carbon nitride (B-g-C3N4), as a potential solution. Developed
through two steps using hydrothermal self-assembly and thermal polymerization,
B-g-C3N4 exhibits a distinctive tubular structure. The unique tubular structure
remarkably increases its surface area and optical absorption, effectively degrading
DCF under visible light. Compared to pure g-C3N4, the B-g-C3N4 material has a
slightly increased surface area (from 14.83 to 16.47 m2 g−1). Moreover, the
incorporation of boron into the g-C3N4 matrix narrows the energy band gap from
2.74 eV to 2.67 eV, allowing the B-g-C3N4 to absorb more effectively in the visible
light region. As a result, more electron-hole pairs are generated, effectively
initiating the photocatalytic degradation process. As a result, B-g-C3N4 exhibits
remarkable efficiency in degrading DCF, achieving nearly 99% elimination in 60
min under visible light illumination. The outcome emphasizes the potential of B-g-
C3N4 as a promising choice for environmental remediation applications.
Keyword(s): Supramolecular self-assembly Graphitic carbon nitride (g-C3N4) Diclofenac (DCF) Photocatalyst Visible light
Pages (from-to) | 88-94 |
Journal | TNU Journal of Science and Technology |
Volume | 230 |
Issue number | 06 |
Publication status | Published - Dec-2024 |
ISBN | 1859-2171 |