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SOLVENT EXTRATION OF ZIRCONIUM(IV) IN SUNFURIC ACID SOLUTION BY HIGH AMINE CETYL TRIMETHYL AMMONI BROMIDE/CCl4
Home Research Publications SOLVENT EXTRATION OF ZIRCONIUM(IV) IN SUNFURIC ACID SOLUTION BY HIGH AMINE CETYL TRIMETHYL AMMONI BROMIDE/CCl4

SOLVENT EXTRATION OF ZIRCONIUM(IV) IN SUNFURIC ACID SOLUTION BY HIGH AMINE CETYL TRIMETHYL AMMONI BROMIDE/CCl4

A T. N. T., M N. C., 2016, In: TNU Journal of Science and Technology, 12/1, 157, p. 35-40

Overview

Abstract:

The paper investigated results effect of the conditions on absorbance of ZrXO, that: the optimal absorption wavelength was 535nm, the optimal concentration of H2SO4 was 0,35M, the volume ratio of 5.10-3M Zr and 5.10-3M XO was 5.0/5.2. Established a calibration curve to determine concentration of Zr(IV) at 535nm in the linear concentrations range from 10-4 - 5.10-3M. Research results effect on extraction efficiency of Zr(IV), including: with 0.35M H2SO4 for E = 72.27%; with Vo/Va = 1/1, E = 72.27%; contact time of two phases and equilibrium separation time of two phases were 20 minutes, E = 72.27%; [Na2SO4]] = 0.25M, that the best effect on the extraction efficiency Zr(IV). Special, we introducted some characteristics of the extraction system Zr-H2SO4-CTAB, that were: built extraction isotherms of Zr(IV) at concentrations of (0.05-1.0M) H2SO4; according the Mc Cable-Thiele plot with Vo/Va=1/1 the degrees of the theory extraction of Zr(IV) were 4 and Vo/Va = 2/1 were 2; extracts 96.52% of Zr(IV) from Zr(IV) 5.10-3M through 5 times extraction; loading organic (LO) of 10-4M CTAB/CCl4 was determined to be 0.4455 g/L Zr(IV) through 5 times of phases contact.

Pages (from-to) 35-40
Journal TNU Journal of Science and Technology
Volume 12/1
Issue number 157
Publication status Published - 2016
ISBN 1859-2171